The industrial production of formic acid via the synthesis of methyl formate from carbon monoxide (CO) and methanol (CH₃OH), followed by hydrolysis, is a process that has gained attention for its efficiency and sustainability. Here's an overview of the technology involved:
● Carbon monoxide and methanol are reacted under high pressure in the presence of a suitable catalyst to produce methyl formate.
● The methyl formate is then hydrolyzed with water to yield formic acid and regenerate methanol, which can be recycled back into the process.
Technical Features
High Efficiency: The direct carbonylation of methanol to methyl formate is a well-established and relatively high-yield process.
Renewable Feedstock: Methanol can be produced from renewable sources like biomass or via CO₂ utilization.
Recycling of Methanol: The hydrolysis step regenerates methanol, which can be recirculated, reducing material waste and improving overall process sustainability.
Formic Acid Specification
Item |
Index |
|
94% |
90% |
85% |
|
Superior grade |
First grade |
Conformed grade |
Superior grade |
First grade |
Conformed grade |
Superior grade |
First grade |
Conformed Grade |
Formic acid, wt% |
≥94.0 |
≥90.0 |
≥85.0 |
Color/Hazen Unit (Pt-Co Color) |
≤10 |
≤20 |
≤10 |
≤20 |
≤10 |
≤20 |
≤30 |
Dilution Test (Sample + Water = 1+3) |
Not turbid |
Passes test |
Not turbid |
Passes test |
Not turbid |
Passes test |
Chloride (as per Cl), wt% |
≤0.0005 |
≤0.001 |
≤0.002 |
≤0.0005 |
≤0.002 |
≤0.002 |
≤0.004 |
≤0.006 |
Sulphate (as per SO4), wt% |
≤0.0005 |
≤0.001 |
≤0.005 |
≤0.0005 |
≤0.001 |
≤0.005 |
≤0.001 |
≤0.002 |
≤0.020 |
Iron (as per Fe), wt% |
≤0.0001 |
≤0.0004 |
≤0.0006 |
≤0.0001 |
≤0.0004 |
≤0.0006 |
≤0.0001 |
≤0.0004 |
≤0.0006 |
Evaporation Residue, wt% |
≤0.006 |
≤0.015 |
≤0.020 |
≤0.006 |
≤0.015 |
≤0.020 |
≤0.006 |
≤0.020 |
≤0.060 |