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PPC (polypropylene carbonate)

PPC (polypropylene carbonate) is a completely biodegradable environmental-friendly plastic synthesized from carbon dioxide and propylene oxide. Besides, due to its using the main source of greenhouse gases—CO₂ as the feedstock, PPC not only reduces the emission of greenhouse gases, but also reduces the consumption of fossil fuel. Compared to the degradable PLA (polylactide), it has advantages of high strength, good ductility, lower production cost and etc. PPC polyol with low molecular weight are used to replace conventional petroleum-based polyether, polyester and polycarbonate polyols, while PPC with high molecular weight are employed as film products, oxygen barrier material, injection molding material and etc., especially in package industry and agriculture.

Introduction

PPC (polypropylene carbonate) is a completely biodegradable environmental-friendly plastic synthesized from carbon dioxide and propylene oxide. Besides, due to its using the main source of greenhouse gases—CO₂ as the feedstock, PPC not only reduces the emission of greenhouse gases, but also reduces the consumption of fossil fuel. Compared to the degradable PLA (polylactide), it has advantages of high strength, good ductility, lower production cost and etc. PPC polyol with low molecular weight are used to replace conventional petroleum-based polyether, polyester and polycarbonate polyols, while PPC with high molecular weight are employed as film products, oxygen barrier material, injection molding material and etc., especially in package industry and agriculture.
SL-TECH offers high molecular weight PPC production technology, with development history as below:
In 1998, the research of CO₂ based plastic began;
In 2001, the first over 1,000 TPA PPC pilot line was built and successfully accepted;
In 2012, 30,000 TPA PPC production line was built and successfully put into production;
In 2013, the technology was upgraded to increase the molecular weight to 300,000;
In 2016, a 30,000 TPA PPC plant using new technology is under construction.
Technical Features
● The number-average molecular weight of PPC using our technology reaches to about 100,000, achieving the most advanced level in the world.
● The tertiary catalyst ensures shorter polymerization time, i.e., 8 hrs, and within 8 hours the catalyst activity can reach a very high level.
● For the production of per ton of PPC product, about 0.45~10.5 MT of carbon dioxide will be consumed. It not only makes use of the CO₂ , but also the PPC product is completely biodegradable and thereby reduces “white pollution”.
Ttypical product specification
S/N Item Index
1 Appearance White or colorless transparent granule
2 Density,g/cm³ 1.24~1.27
3 Number-Average Molecular Weight, kg/mol 200~300
4 Glass Temperature 35~39
5 CO₂ Content, wt% 40%~42%
6 5% Decomposition Temperature, ­°C >230
7 Processing Temperature,°C 140~190
8 Moisture Content, wt% <0.3%
9 Ash,ppm <1000
10 Bio-gradability Under forced composting, will be decomposed within 3 months
Product mechanical properties and transparency
Density(g/cm³ ) Melting index (g/10min) Tg (°C ) Tensile Strength (Mpa) Tensile Modulus (Mpa) Elongation at break (%) Impact Strength (g)V Transmittance
1.25~1.30 0.2~10 35~38 40~45 1000 15~20 <35 94~95%
20°C 160°C ,2.16 Kg DSC 100 C/min 20℃,50 mm/min 20℃,50 mm/min 20℃,50 mm/min 20℃,falling dart impact 0.2mm film, 400~800nm

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